A technological acceptance of e-learning tools used in practical and laboratory teaching, according to the European higher education area

The application of scientific tools to analyse the use of Internet-based e-learning tools in academic settings is in general an ignored area. E-learning tools are actually an emergent topic as a result of the new ideas introduced by the European Higher Education Area. Lifelong learning, or the promotion of student initiative, is the new paradigm of a learner-centred education. In this context, e-learning tools can represent an effective way of supporting this new trend in education. Assuming the premise that successful use of these web-based tools depends primarily on a user’s behaviour, the objective of this research is to examine the technology acceptance model (TAM) of web-based elearning tools used in practical and laboratory teaching. The research hypotheses derived from this model have empirically been validated using the responses to a survey on e-learning usage among 220 users. These responses have been examined through partial least square. The obtained results strongly support the extended TAM in predicting a student’s intention to use e-learning and define a set of external variables with a significant influence in the original TAM variables. Surprisingly, perceived ease of use did not posit a significant impact on student attitude or intention towards e-learning tool usage. Therefore, early evaluation of e-learning material is considered essential to providing a framework for further improvements of the too

Simultaneous J-, H-, K- and L-band spectroscopic observations of galactic Be stars. I. IR atlas

It is already accepted that Be stars are surrounded by circumstellar envelopes, which are mostly compatible with a disc geometry in Keplerian rotation. We aim to obtain a more complete characterisation of the properties of the circumstellar environment of Be stars that helps to constrain the theoretical models of the Be phenomenon. We present near-infrared, medium-resolution spectra of a sample of galactic Be stars with different spectral subtypes and luminosity classes. We measure different parameters of the hydrogen recombination lines from the Paschen, Brackett, Pfund, and Humphreys series, and use them to diagnose physical conditions in the circumstellar environment. We analysed the equivalent-width (EW) ratio between Br$\alpha$ and Br$\gamma$ lines and different diagrams of flux ratios. We also identify lines from He I, C I, N I, O I, Na I, Mg I, Mg II, Si I, Fe I, and Fe II. Analysing the EW measurements of particular He I, Mg II, Fe I, Fe II and O I lines, we find that for some lines they correlate with the spectral type of the star. Particularly, the emission of the O I~$\lambda\,1.3168\,\mu$m line decreases towards the later spectral types. We present an atlas of 22 Be stars, that covers a wide infrared (IR) spectral range with quasi-simultaneous observations. From a detailed analysis, we define new complementary criteria to Mennickent's classification of Be stars according to their disc opacity. Some objects in our sample present compact thick envelopes, while in others the envelope is extended and optically thin. The correlation between the full widths at half maximum (FWHM) and the peak separation ($\Delta \mathrm{V}$) versus $V\,\sin\,i$ for the Br10, Br$\delta$, and Hu14 lines reveals that the broadening mechanism is rotational. The Ly$\beta$ fluorescence is a key mechanism to explain the intensity of the emission of Mg II and O I lines.Comment: 27 pages, 14 figures. Accepted for publication in A&

Inhomogeneous molecular ring around the B[e] supergiant LHA 120-S 73

We aim to improve our knowledge on the structure and dynamics of the circumstellar disk of the LMC B[e] supergiant LHA 120-S 73. High-resolution optical and near-IR spectroscopic data were obtained over a period of 16 and 7 years, respectively. The spectra cover the diagnostic emission lines from [CaII] and [OI], as well as the CO bands. These features trace the disk at different distances from the star. We analyzed the kinematics of the individual emission regions by modeling their emission profiles. A low-resolution mid-infrared spectrum was obtained as well, which provides information on the composition of the dusty disk. All diagnostic emission features display double-peaked line profiles, which we interpret as due to Keplerian rotation. We find that LHA 120-S 73 is surrounded by at least four individual rings of material with alternating densities (or by a disk with strongly non-monotonic radial density distribution). Moreover, we find that the molecular ring must have gaps or at least strong density inhomogeneities, or in other words, a clumpy structure. The mid-infrared spectrum displays features of oxygen- and carbon-rich grain species, which indicates a long-lived, stable dusty disk. We cannot confirm the previously reported high value for the stellar rotation velocity. The line profile of HeI 5876 A is strongly variable in both width and shape and resembles of those seen in non-radially pulsating stars. A proper determination of the real underlying stellar rotation velocity is hence not possible. The existence of multiple stable and clumpy rings of alternating density recalls ring structures around planets. Although there is currently insufficient observational evidence, it is tempting to propose a scenario with one (or more) minor bodies or planets revolving around LHA 120-S 73 and stabilizing the ring system, in analogy to the shepherd moons in planetary systems.Comment: 14 pages, 13 figure, accepted for pulication in A&

Machine Learning Models that Remember Too Much

Machine learning (ML) is becoming a commodity. Numerous ML frameworks and services are available to data holders who are not ML experts but want to train predictive models on their data. It is important that ML models trained on sensitive inputs (e.g., personal images or documents) not leak too much information about the training data. We consider a malicious ML provider who supplies model-training code to the data holder, does not observe the training, but then obtains white- or black-box access to the resulting model. In this setting, we design and implement practical algorithms, some of them very similar to standard ML techniques such as regularization and data augmentation, that "memorize" information about the training dataset in the model yet the model is as accurate and predictive as a conventionally trained model. We then explain how the adversary can extract memorized information from the model. We evaluate our techniques on standard ML tasks for image classification (CIFAR10), face recognition (LFW and FaceScrub), and text analysis (20 Newsgroups and IMDB). In all cases, we show how our algorithms create models that have high predictive power yet allow accurate extraction of subsets of their training data

Posibilidades de reproducción de Schinus johnstonii (Anacardiaceae), una especie nativa del Monte argentino

Schinus johnstonii F. A. Barkley (Anacardiaceae) es un arbusto nativo de la ProvinciaFitogeográfica del Monte, donde representa un importante componente del pastizal natural. Su tolerancia a la sequía, junto a la presencia de una floración abundante,la convierten en una buena opción para proyectos paisajísticos y de restauración de ambientes degradados y deforestados. Para tales fines es necesario contar con informaciónacerca de sus posibilidades de reproducción. Los objetivos de este trabajo fueron determinar los requerimientos básicos para la germinación de sus semillas(reproducción sexual), en condiciones de laboratorio, la viabilidad de las mismas y analizar la supervivencia de estacas (reproducción vegetativa), en condiciones controladasy bajo distintos tratamientos. Las semillas recolectadas se sometieron a seis tratamientos pre-germinativos: exocarpo intacto (control), remoción de exocarpo(desnudas), semillas desnudas con escarificación mecánica, semillas desnudas con escarificación química, semillas desnudas en remojo y semillas desnudas con exposicióna humo. Sólo se observó germinación en semillas sin exocarpo. Las semillas desnudas germinaron a partir de los 10 días, con un valor máximo del 38%, sinencontrarse diferencias entre los tratamientos. Se observó, además, una importanteproporción de semillas no viables o vacías (30-40%). El estudio de reproducciónvegetativa, con estacas recolectadas durante los estadios fenológicos vegetativo yreproductivo, con y sin hormona de enraizamiento, dio como resultado un porcentajebajo de rebrote (20%), sin diferencias entre tratamientos. Según los resultados,las semillas de S. johnstonii presentarían dormición física impuesta por la cubierta(superada por remoción del exocarpo). La reproducción de este arbusto no seríarecomendable por medio de estacas, aunque se sugiere realizar más estudios.Schinus johnstonii F. A. Barkley (Anacardiaceae) is a native shrub to the Monte Phytogeographic Province, where it represents an important component of rangelands. Its tolerance to drought and abundant flowering, render it a good option for landscaping and land restoration projects on degraded and deforested areas. For such purposes, information about its reproductive possibilities is needed. The objectives of this work were to determine the basic requirements for seed germination (sexual reproduction) under laboratory conditions, viability and to analyze the survival of cuttings (vegetative reproduction), under controlled conditions and different treatments. The collected seeds were subjected to six pre-germination treatments: intact exocarp (control), exocarp removal (bare), bare seeds with mechanical scarification, bare seeds with chemical scarification, bare seeds with soaking and bare seeds with exposure to smoke. Germination was only observed in seeds without exocarp. Bare seeds germinated after 10 days, with a maximum value of 38%, with no differences between treatments. In addition, a significant proportion of non-viable or empty seeds (30-40%) was observed. The vegetative reproductive study, with cuttings collected during the vegetative and reproductive phenological stages, with and without rooting hormone, resulted in a low percentage of regrowth (20%), with no differences between treatments. According to these results, seeds of S. johnstonii would present physical dormancy imposed by the seed coat (overcome by the removal of the exocarp). The reproduction of this shrub by cuttings is not recommended, although further studies are suggested

In vitro and in vivo leishmanicidal studies of Peperomia galioides (Piperaceae)

Petroleum ether and methylene chloride extracts of #Peperomia galioides and three phenylated diphenols, grifolic acid, grifolin and piperogalin exhibited in vitro antileishmanial activity. During the course of infection of BALB/c mice with #Leishmania amazonensis, the treatments with each of these compounds did not influence the progression of the disease. (Résumé d'auteur

A first--order irreversible thermodynamic approach to a simple energy converter

Several authors have shown that dissipative thermal cycle models based on Finite-Time Thermodynamics exhibit loop-shaped curves of power output versus efficiency, such as it occurs with actual dissipative thermal engines. Within the context of First-Order Irreversible Thermodynamics (FOIT), in this work we show that for an energy converter consisting of two coupled fluxes it is also possible to find loop-shaped curves of both power output and the so-called ecological function against efficiency. In a previous work Stucki [J.W. Stucki, Eur. J. Biochem. vol. 109, 269 (1980)] used a FOIT-approach to describe the modes of thermodynamic performance of oxidative phosphorylation involved in ATP-synthesis within mithochondrias. In that work the author did not use the mentioned loop-shaped curves and he proposed that oxidative phosphorylation operates in a steady state simultaneously at minimum entropy production and maximum efficiency, by means of a conductance matching condition between extreme states of zero and infinite conductances respectively. In the present work we show that all Stucki's results about the oxidative phosphorylation energetics can be obtained without the so-called conductance matching condition. On the other hand, we also show that the minimum entropy production state implies both null power output and efficiency and therefore this state is not fulfilled by the oxidative phosphorylation performance. Our results suggest that actual efficiency values of oxidative phosphorylation performance are better described by a mode of operation consisting in the simultaneous maximization of the so-called ecological function and the efficiency.Comment: 20 pages, 7 figures, submitted to Phys. Rev.

Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films

[EN] In the present study, agro-food waste derived rice straw (RS) was valorized into cellulose microfi-bers (CMFs) using a green process of combined ultrasound and heating treatments and were, thereafter, used to improve the physical properties of thermoplastic starch films (TPS). Mechanical defibrillation of the fibers gave rise to CMFs with cumulative frequencies of length and diameters below 200 and 5¿15 µm, respectively. The resultant CMFs were successfully incorporated by melt mixing into TPS and also starch subjected to dry heating (DH) modification to yield TPS modified by dry heating (TPSDH) by thermo-compression and characterized. It was observed that both DH modification and fiber incorporation at 3 and 5 wt% loadings interfered with the starch gelatini-zation, leading to non-gelatinized starch granules in the biopolymer matrix. Thermo-compressed films prepared with both types of starches that wereand reinforced with 3 wt% CMF were more rigid (percentages increases of ~215% for TPS and ~207% for the TPSDH), more resistant to break (~100% for TPS and ~60% for TPSDH), but also less extensible (~53% for TPS and ~78% for TPSDH). The incorporation of CMFs into the TPS matrix at both contents also promoted a de-crease in water vapor (~15%) and oxygen permeabilities (~30%). Finally, the TPS composite films showed low changes in terms of optical properties and equilibrium moisture, being less soluble in water than the TPSDH films.This research was funded by Spanish Ministry of Science and Innovation (MICI), grant number PID2019-105207RB-I00.Vieira-De Freitas, PA.; La Fuente Arias, CI.; Torres-Giner, S.; González Martínez, MC.; Chiralt Boix, MA. (2021). Valorization of Rice Straw into Cellulose Microfibers for the Reinforcement of Thermoplastic Corn Starch Films. Applied Sciences. 11(18):1-20. https://doi.org/10.3390/app11188433S120111